Terahertz calorimetry bridges intermolecular vibrational interactions and solvation enthalpy and entropy changes during minute and fast processes. It can, for example, probe the intermolecular ...

Ranges of maps as those indicated are called information diagrams. The main result gives rise to precise lower as well as upper bounds for the entropy function. Some of these bounds are essential for ...

A method is presented to evaluate a molecule’s entropy from the atomic forces calculated in a molecular dynamics simulation. Specifically, diagonalization of the mass-weighted force covariance matrix ...

We present an experimental Raman study on how the addition of sodium chloride to CO2-hydrate-forming systems inhibits the hydrate formation thermodynamically. For this purpose, the molar enthalpy of ...

By means of non-linear enthalpy-entropy compensation analysis, it follows that the dissolution process of this drug in ethanol-rich mixtures is entropy-driven, whereas, in water-rich mixtures the ...